New paper from Judith (PhD thesis, paper No.3)

2019-01-29

Mehlhorn, J; Gerber, L; Planer-Friedrich, B: Spatial distribution of metal(loid) depletion and accumulation zones around a natural carbon dioxide degassing site, Chemical Geology (2019), doi:10.1016/j.chemgeo.2019.01.010 

https://authors.elsevier.com/c/1YUG-26gaVbmk

Long-term influence of geogenic CO₂ affects soil conditions and pedogenesis. Mobilization of metals and metalloids from soil to solution has been reported to occur in natural CO₂ degassing sites, so-called mofettes. We determined metal(loid)-specific spatial distribution patterns in soil around a mofette as well as metal(loid) pore water concentrations along a CO₂ gradient (0–98% CO₂ in soil air). Depletion of Mn, Co, and Ni in soil in the mofette center was caused by leaching due to the long-term soil acidification leading to correspondingly low pore water concentrations and thus indicating no recent influence of CO₂ on metal(loid) mobility. Iron and As were also depleted in soil within the mofette center where pedogenic Fe (oxyhydr)oxides could not form due to absence of oxygen. Small-scale variations in redox conditions lead to ongoing Fe cycling and the repeated reduction of Fe (oxyhydr)oxides resulted in increased Fe and As pore water concentrations at high CO₂. Precipitation in form of sulfide minerals caused immobilization and accumulation of Cd, Cu, and Zn directly in the degassing center. The highest mobilization risk occurred within 2–4 m distance from the degassing center, where complexation with dissolved organic matter (DOM) increased the mobility of Al, As, Cr, Cu, Fe, and Zn. Our results show that CO₂ as soil-forming factor influences the spatial distribution of metal(loid)s. The highest metal(loid) mobilization risk after long-term CO₂ influence arises from accumulation of scarcely degraded organic matter, which can easily dissolve and form mobile metal(loid)-DOM complexes.